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So, if we hybridize just these three orbitals, what we're going to end up with is our s p 2 hybrid orbitals.
我们会看到现在有3个未配对的电子，可以成键。
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So we can have, if we have the final quantum number m equal plus 1 or minus 1, we're dealing with a p x or a p y orbital.
所以如果我们有,磁量子数ｍ等于正负１,我们讨论的就是ｐｘ或者ｐｙ轨道。
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The structures in the brain which would underwrite the ability to engage in P-functioning, they're not destroyed by suspended animation.
存在于大脑中的,能够支持人格功能的结构，并没有被假死状态所破坏。
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And for a couple of reasons, one this is the first P set where we're actually gonna give you code to work from.
由于一些原因，这里是第一个习题集,在此我们提供了一些代码供大家参考。
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And if you're below this temperature here, this quantity, p times v it would be negative.
压强与体积的乘积将变成负数，这可能吗？
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Again, so as we don't get confused, normally we use S for strategy, but let's use P since they're prices.
为了避免混淆,通常我们用S表示策略,但是这次我们使用P,因为它代表价格
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Well, the initially tempting thing to say is not only aren't you broken, but you're actually engaged in P-functioning.
首先要说的会是,不仅你没有被破坏，还有确实,拥有人格功能性。
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It's 109 . 5 is what we would expect for methane because it's tetravalent, but here we're just seeing something that's divalent, and they're both in p orbitals that are perpendicular to each other.
因为甲烷是四价的，我们预测是109。,但这里我们，看到的是二价的，它们都在。
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It's somewhat different when we're talking about the p or the d orbitals, and we won't go into the equation there, but this will give you an idea of what we're really talking about with this radial probability distribution.
当我们讨论ｐ轨道或者,ｄ轨道的时候会有些不同，我们那时不会给出方程，但它会给你们一个,关于径向概率,分布的概念。
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So we're going to have to revise the P-functioning or the end of P-functioning theory of death.
我们要修改人格功能,或者人格功能的完结代表死亡这一说法。
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So let's fill it out in this way, 2p keeping in mind that we're going to fill sigma out the pi 2 p's before the sigma.
让我们这样填上去，记住我们先填π,轨道再填。
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They were only temporarily not P-functioning, just like we are temporarily not P-functioning when we're asleep.
只是暂时失去了人格功能性，就像我们睡觉时,暂时没有人格功能性一样。
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px We'll call it either pi 2 p x, 2py if we're combining the x orbitals, or pi 2 p y.
我们叫它π,如果是x轨道组合的话，或者π
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It's okay if you're not P-functioning, as long as your not P-functioning is temporary.
没有人格功能性是可以的，只要这个阶段是暂时的。
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The same thing when you're going from filling in the 2 s to putting that first electron into the 2 p.
当你填满，2，s，后再往，2，p，中,放第一个电子的时候就会发生这种问题。
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If you will P-function again, if you have been P-functioning in the past and you will be P-functioning again in the future, P-functioning for person functioning, you will be P-functioning again in the future, then you're not dead.
只要你还可能再度拥有人格功能性，以前有过人格功能性,以后也会有人格功能性，人格功能性就是作为人的各种功能，你将来能够再次拥有人格功能性，你就没有死。
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But unlike the case with boron where we had an empty p orbital, we're actually going to have an electron in the p orbital of carbon as well.
但和硼里面有个空的p轨道不同，我们实际上有一个电子,在碳里p轨道里也有电子。
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So it's along the bond axis and it's between a carbon s p 2 hybrid, and then the hydrogen is just a 1 s orbital that we're combining here.
所以它是沿着键轴方向的,而且这里是一个碳sp2杂化轨道，和一个氢的1s轨道的结合,在这里我们可以合并他们。
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We want a relationship in p-V space, not in T-V space. So we're going to have to do something about that. But first, it turns out that now we have this R over Cv.
我们想要p-V空间中的结果，而不是T-V空间中的,因此需要做一些变换，先来看现在的关系，它跟R/Cv有关。
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And it turns out that when you constructively have two p orbitals interfere, and when I say constructively, I mean they're both either positive or they're both the negative lobes, that's when you got bonding.
当两个ｐ轨道,相长干涉时，我说的相干相长，意思就是说它们要么都是,正的叶瓣要么都是负的叶瓣，这时就能成键。
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Your P-functioning is actualized now, because you're engaged in thought, but you don't lose the ability to think during those moments when you're not thinking.
你的能力正在被实践，是因为你正在思考，但你没有在思考的时候也没有,失去思考的能力。
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We might say, look, while you're asleep, it's true that you're not P-functioning.
我们可以说，看，当你睡着时，确实没有人格功能性。
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In case 2, we're taking the 3 p out of the neutral atom, whereas in case 3, we're taking it out of the ion.
在第二种情况中，我们要从中性原子中拿走，3，p，电子，而在第三种情况中，我们要从这个离子中拿走它。
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All right. So let's look now at the case where we do have 2 p z orbitals that we're talking about.
好的，让我们现在看一个,需要2pz轨道的例子。
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Of such a person we might say, they're no longer capable of P-functioning.
有人也许会说，他们已经没有人格功能能力。
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If we say that to be a person is to be a P-functioning body, it seems then as though we have to conclude that when you're not P-functioning, you're dead.
如果说人是一个有人格功能性的实体，似乎就能得出以下结论,如果你没有人格功能性，你就是死亡的。
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Well, that's at least an improvement, because then we say, look, while you're asleep, even though there's no P-functioning going on, the lack of P-functioning is temporary, so you're still alive.
这至少算是个改进，因为我们能说，看，你睡着了，即便没有任何人格功能性发生，人格功能性的缺少是暂时的，就说明你还活着。
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they're not engaged in P-functioning. That's pretty clear.
他们没有人格功能性，这点很明白。
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Well, now they're P-functioning.
他们再度拥有人格功能性。
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