• In other words, just want to know where the electron is somewhere within the shell radius of the ground state of atomic hydrogen anywhere.

    换言之,我只是想知道,电子在哪,可以在氢原子基态下的半径,里面的任何地方。

    麻省理工公开课 - 固态化学导论课程节选

  • But still, when we're talking about the radial probability distribution, what we actually want to think about is what's the probability of finding the electron in that shell?

    但当我们讲到径向概率分布时,我们想做的是考虑,在某一个壳层里,找到电子的概率,就把它想成是蛋壳?

    麻省理工公开课 - 化学原理课程节选

  • They have the highest average valence electron energy in any shell.

    它们有最大的价电子能,任意一层都是这样。

    麻省理工公开课 - 固态化学导论课程节选

  • So here we're talking about v plus 1, so if we were to write it just for the neutral electron itself, we would find that the electron configuration is argon, that's the filled shell in front of it.

    这里我们要分析的是正一价的钒离子,因此,我们先写出中性原子的电子排布,可以发现,其原子实是氩原子的电子排布,这些壳层已经被占满了。

    麻省理工公开课 - 化学原理课程节选

  • r And what that is the probability of finding an electron in some shell where we define the thickness as d r, some distance, r, from the nucleus.

    在某个位置为,厚度为dr的壳层内,找到原子,的概率,我们来考虑下我们这里所说的。

    麻省理工公开课 - 化学原理课程节选

  • This should make sense to you, because they don't, in fact, want to gain another electron, because that would mean that electron would have to go into a new value of n, a new shell, and that's really going to increase the energy of the system.

    这对大家来说应该容易理解,因为它们实际上不想得到另一个电子,因为这意味着这个电子不得不,到一个新的,n,值更大的壳层上去,这将会增加系统的能量。

    麻省理工公开课 - 化学原理课程节选

  • If you look at oxygen, oxygen is 1s2, which is an inner shell electron.

    你看,氧是1s2原子,1s轨道上是内层电子。

    麻省理工公开课 - 固态化学导论课程节选

  • So basically, that means one electron in an s orbital in their outer-most most shell.

    因此基本上,这意味着那个在,s,轨道上价电子是最外层的。

    麻省理工公开课 - 化学原理课程节选

  • So there are two electron configurations in the n equals one shell, if we follow according to the selection rules that we spelled out last day.

    如果根据上次课,我们阐明的原子光谱选择定则,我们就会知道在n等于1的那一层,有两种电子图像构型。

    麻省理工公开课 - 固态化学导论课程节选

  • The other main difference that we're really going to get to today is that in multi-electron atoms, orbital energies depend not just on the shell, which is what we saw before, not just on the value of n, but also on the angular momentum quantum l number. So they also depend on the sub-shell or l.

    我们今天要讨论的,另一个很重要的区别就是,在多电子原子中,轨道能力不仅仅依赖于,我们以前看到的外层,不仅仅依赖于n的值,而是与角动量量子数也有关系,所以它们也依赖于亚外层或者。

    麻省理工公开课 - 化学原理课程节选

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